using DevExpress.XtraReports.UI;
using DevExpress.XtraPrinting.BarCode;
// ...

private void button1_Click(object sender, System.EventArgs e) {
    XtraReport1 report = new XtraReport1();

    // Create a barcode control.
    XRBarCode barcode = new XRBarCode();

    // Set the barcode's type to Matrix 2 of 5.
    barcode.Symbology = new Matrix2of5Generator();

    // Adjust the Matrix 2 of 5 barcode's main properties.
    barcode.Text = "0123456789";
    barcode.Width = 400;
    barcode.Height = 100;

    // Adjust the Matrix 2 of 5 barcode's specific properties.
    ((Matrix2of5Generator)barcode.Symbology).CalcCheckSum = false;
    ((Matrix2of5Generator)barcode.Symbology).WideNarrowRatio = 3;

    report.Detail.Controls.Add(barcode);
    report.ShowPreview();
}

Imports DevExpress.XtraReports.UI
Imports DevExpress.XtraPrinting.BarCode
' ...

Private Sub Button1_Click(ByVal sender As Object, ByVal e As System.EventArgs) _
Handles Button1.Click
    Dim report As New XtraReport1()

    ' Create a barcode control.
    Dim Barcode As New XRBarCode()

    ' Set the barcode's type to Matrix 2 of 5.
    Barcode.Symbology = New Matrix2of5Generator()

    ' Adjust the Matrix 2 of 5 barcode's main properties.
    Barcode.Text = "0123456789"
    Barcode.Width = 400
    Barcode.Height = 100

    ' Adjust the Matrix 2 of 5 barcode's specific properties.
    Dim Matrix2of5Symbology As Matrix2of5Generator = Barcode.Symbology
    Matrix2of5Symbology.CalcCheckSum = False
    Matrix2of5Symbology.WideNarrowRatio = 3

    report.Detail.Controls.Add(Barcode)
    report.ShowPreview()
End Sub